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This study seeks to understand the role of photodegradation of aqueous polymers in drop splashing. Polymer drop impact commonly occurs in various industrial applications such as inkjet printing, spray coating, and agrochemical sprays. In agrochemicals, the various constituent components (e.g., adjuvants) imparts multiple changes to the fluid dynamics and the wetting behaviors of the drops, as well as interacting with the environmental conditions. The environmental conditions (e.g., thermal-degradation, photo-degradation, and oxidation) of the chemicals affect the shelf stability of the intended physicochemical properties of the chemicals, which are added to stabilize drift from the spray nozzles and minimize drop bouncing from leaves. The aging effects of the adjuvants in tandem with the already low pesticide delivery efficiency has an unknown effect on the agrochemical delivery efficiency and the related environmental burden from the increased run off. Herein, we systematically photo-degraded polyethylene oxide (PEO) to probe the drop splashing behavior as a result of the simulated aging conditions. Dye was added to accelerate the degradation of the polymers and caused drops to splash at Weber numbers where the pure PEO case did not, confirming the need to consider environmental factors which contributes to adjuvant aging in agrochemical applications. We have also conducted experiments with various concentrations of PEO to probe the changes in the splash dynamics as well as including surfactants, which played a marginal role in altering the splash dynamics under our parameter space. The significance of the study is that the degradation of the polymers influences the splashing and increases the amount of splashed droplets, indicating the importance of controlling the environmental conditions under which polymer solutions are stored. 

In the South Island of Aotearoa (New Zealand), the preservation of biogenic carbonate in Late Triassic sedimentary rocks is rare to non-existent; however, differential preservation modes between common phyla are commonly observed and serve to elucidate the stratigraphic and diagenetic history of these often poorly- exposed immature sandstone units. The Taringatura Group sandstones from Southland and Otago range from sandy siltstones to silty arkosic sandstones that commonly host molluscan and brachiopod macrofossils as well as rare echinoderms, bryozoans, and foraminifera. Additionally, there is a hypothesized unconformity between the lower Oretian and Otamitan age (227.7–217.0 Ma) and the overlying Warepan age (217–208.5 Ma) deposits indicated by an abrupt change in composition, grain size, and fossil assemblage. Molluscs from the Oretian and Otamitan deposits exhibit fine-detail preservation on external and internal molds. Thin-shelled taxa, such as Halobia, exhibit some shell replacement by clay minerals, likely from the dissolution of feldspars in the surrounding rock. Conversely, larger and thicker-shelled brachiopods and bivalves such as Manticula and Hokonuia do not present as casts. When preserved, foraminifera and rare bryozoans are typically silicified. The overlying Warepan sandstone beds frequently contain fossils of the bivalve Monotis which exhibit a similar preservation style to older molluscs, though lacking clay minerals. Presently, the fossiliferous Taringatura sandstones exhibit low porosity and low permeability, as is expected from the subsequent compaction of sandstones after burial. However, the dissolution of biogenic carbonate implies a past permeability. The presence of clay minerals in Oretian and Otamitan fossils may indicate a period of subaerial exposure and infiltration of meteoric water prior to the deposition of Warepan units. Notably, clay replacement occurs more frequently in the thinnest fossils. Original carbonate material may have persisted for longer in the more robust taxa, allowing them to resist most deformation from compaction prior to the final loss of carbonate. Differential diagenesis of biogenic carbonates supports the existence of a significant unconformity between Otamitan and Warepan units in the Taringatura sandstones. 

Fire-prone landscapes found throughout the world are increasingly managed with prescribed fire for a variety of objectives. These frequent low-intensity fires directly impact lower forest strata, and thus estimating surface fuels or understory vegetation is essential for planning, evaluating, and monitoring management strategies and studying fire behavior and effects. Traditional fuel estimation methods can be applied to stand-level and canopy fuel loading; however, local-scale understory biomass remains challenging because of complex within-stand heterogeneity and fast recovery post-fire. Previous studies have demonstrated how single location terrestrial laser scanning (TLS) can be used to estimate plot-level vegetation characteristics and the impacts of prescribed fire. To build upon this methodology, co-located single TLS scans and physical biomass measurements were used to generate linear models for predicting understory vegetation and fuel biomass, as well as consumption by fire in a southeastern U.S. pineland. A variable selection method was used to select the six most important TLS-derived structural metrics for each linear model, where the model fit ranged in R2 from 0.61 to 0.74. This study highlights prospects for efficiently estimating vegetation and fuel characteristics that are relevant to prescribed burning via the integration of a single-scan TLS method that is adaptable by managers and relevant for coupled fire–atmosphere models. 

Moving toward a sustainable global society requires substantial change in both social and technological systems. This sustainability is dependent not only on addressing the environmental impacts of current social and technological systems, but also on addressing the social, economic and political harms that continue to be perpetuated through systematic forms of oppression and the exclusion of Black, Indigenous, and people of color (BIPOC) communities. To adequately identify and address these harms, we argue that scientists, practitioners, and communities need a transdisciplinary framework that integrates multiple types of knowledge, in particular, Indigenous and experiential knowledge. Indigenous knowledge systems embrace relationality and reciprocity rather than extraction and oppression, and experiential knowledge grounds transition priorities in lived experiences rather than expert assessments. Here, we demonstrate how an Indigenous, experiential, and community-based participatory framework for understanding and advancing socio-technological system transitions can facilitate the co-design and co-development of community-owned energy systems.